Inorganic Chemistry , 55 11 , Amaia Beloqui Redondo, Flavien L. Morel, Marco Ranocchiari, and Jeroen A. ACS Catalysis , 5 12 , Journal of the American Chemical Society , 41 , Jarad A. Mason, Lucy E. Darago, Wayne W. Lukens, Jr. Inorganic Chemistry , 54 20 , Journal of the American Chemical Society , 36 , Andreas Mavrandonakis, Konstantinos D.
Vogiatzis, A. Inorganic Chemistry , 54 17 , These indicate that the prepared samples have a loose mesoporous structure. The coulombic efficiencies are always over It is noticeable that the Na-reaction potential in the Fe2O3 is quite lower than the Li-reaction potential. In the initial discharge, the potential drops rapidly to a plateau of 1. The plateau is not so apparently, which is possible due to the presence of small nanoparticles of Fe2O3.
The reaction can be described as equation 2 and the conversion of the iron oxide accompanied by the layer formation of solid electrolyte interface SEI. Electrode potential range of 0. Full size image After cycles, the capacity can also be kept at ca. The cyclic voltammograms CVs within the range of 0. The first CV plot is different from those of the subsequent scans, which is attributed to the irreversible formation of a solid electrolyte interface SEI.
In the subsequent cycles, a broad cathodic peak at 0. These results are consistent with CV analysis above and other reports 7 , To investigate electrochemistry performance under the different rate discharge, Fig.
The stable cyclic performance is obtained for all densities. Subsequently, a specific capacity of ca. SEI layer also can be detected accord to the inset in the Fig. Compared with the previous reported iron oxide materials 1 , 7 , 11 , 15 , 32 , 33 , the material reported here is very attractive due to its facile, fast, and improved sodium storage. The nano-scaled characteristics of Fe2O3 particle from MOFs embedded in the aggregates ensure the electrode having a high capacity and the fast Na-ion diffusion in the electrode, and the introduction of carbon renders the electrode having a good electronic conductivity.
The unique hollow structures can shorten the length of Na-ion diffusion, which is benefit for the rate performance. The hollow structure offers a sufficient void space, which sufficiently alleviates the mechanical stress caused by volume change. Experimental section Materials and Methods Synthesis of hollow Fe2O3 precursor All chemicals were of analytical grade and used without further purification. Then 0. Nitrogen adsorption-desorption measurements were conducted at 77 K on a Micromeritics Tristar apparatus.
Specific surface areas were determined following the Brunauer-Emmet-Teller analysis. When 2. While the -NH2 on the adsorbent is deprotonated with increasing the concentration of 0H- under the alkaline conditions.
And thus, it is not favorable for the adsorption process due to the electrostatic repulsion between the adsorbent and the adsorbate. Moreover, excessive OH and H2PO4 competes for adsorption sites, resulting in a decrease in the removal efficiency and adsorption capacity. Effects of mixing time and Kinetics study on the phosphate adsorption. It can be seen that the adsorption capacity increased rapidly in the beginning of the adsorption process and then approached a constant value in Fig.
It is interesting that the time of adsorption only need 30 minutes, which is much shorter than other reports. To quantitatively analyze the kinetics of the phosphate adsorption, plots of qt versus t were further analyzed using the pseudo second order rate laws. The pseudo second order rate law was then used to analyze the kinetics as equation , where k2 g. The estimated qe is 9. To further analyze the adsorption isotherm data, the Langmuir isotherms was employed.
The Langmuir model assumes that the adsorption occurs as a mono-layer on a homogenous surface where the number of adsorptive sites is finite.
Once the adsorptive sites are occupied, they cannot adsorb other adsorbates. Therefore, a maximal adsorption capacity qmax is expected in the Langmuir model which can be described as equation Figure 9.
Furthermore, the separation constant RL is another important property of the Langmuir adsorption isotherm, which is used to characterize the degree of adsorption reaction carried out, and the expression is as equation As shown in Fig. S3, RL decreased with the increase of the initial concentration of phosphorus solution, indicating that increasing the concentration of adsorbed substance is more beneficial to the adsorption Since eutrophic water also contains other anions, it is important to examine the competing adsorption between phosphate and other anions to Fe3O4 NH2-MIL Fe.
Figure 10 reveals that even though the other anions are present in the phosphate solution and c0 of each ion species is 0. The adsorption of above mentioned anions to adsorbents was negligible, showing the prepared Fe3O4 NH2-MIL Fe possessed a high selectivity towards phosphate over the other anions. Moreover, the unique magnetism of the synthesized adsorbents contributes greatly to the fast collection of the disposals after adoption as Fig. S4, which exhibits excellent potential in the process of water treatment.
Additionally, Figs S1-S4 and thermodynamic study on the phosphate adsorption are listed in the supplementary information. Compared with the previous reported adsorbents,20,21, the material reported here is very attractive due to its facile, fast, and improved adsorption activity. Surface functionalization of magnetic hollow materials is a well-designed way to bridge the gap between high adsorption activity and excellent separation and recovery from the water treatment system.
Therefore, these functionalized magnetically adsorbents are increasingly being used in environment, catalysis, green chemistry and pharmaceutically significant reactions. They exhibit excellent adsorption performance for enhanced selective removal of phosphates from aqueous solution.
Moreover, the adsorbents can be easily separated from the reaction system. Compared to other adsorbents, the prepared materials are good recovery application and high adsorption activity due to the unique hollow structure, surface functionalization and good magnetic property. This general strategy may shed light on a novel avenue for the effective synthesis of hollow porous magnetic MOFs for environmental remediation, energy storage, drug delivery, catalyst and other new applications.
Experimental Section Materials and Methods. Synthesis of hollow Fe3O4 precursor. Synthesis of hollow Fe3O4 is according to the improved method All chemicals were of analytical grade and used without further purification. Typically, FeClH2O 1. Then 0. The typical procedure was as follows: 0. Nitrogen adsorption-desorption measurements were conducted at 77 K on a Micromeritics Tristar apparatus.
Specific surface areas were determined following the Brunauer-Emmet-Teller analysis. The magnetization curve was measured at room temperature under a varying magnetic field from to Oe using a BHV vibrating sample magnetometer VSM. The resulting mixture was then placed in a temperature-controllable magnetic stirrer at rpm to begin the adsorption.
The adsorption experiments were performed for 30 min to ensure that the adsorption reached the equilibrium. L-1 is equilibrium concentration of phosphorus and V represents the total volume of solution. The concentration of phosphate in supernatant was analyzed by National standard method of China GB : Water quality-Determination of total phosphorus-Ammonium molybdate spectrophotometry method.
In this study, the effect of the adsorbent dosage was first studied by varying adsorbent dosage from 10 to 80 mg L In addition, the adsorption kinetics of phosphate was determined by mixing 12mg of samples with a 0. L-1 at normal atmospheric temperature. References 1. Wei, W. Johnson, B. Adsorption of organophosphates from solution by porous organosilicates: Capillary phase-separation.
Microporous Mesoporous Mater. Samet, Y. Electrochemical degradation of chlorpyrifos pesticide in aqueous solutions by anodic oxidation at boron-doped diamond electrodes. Karageorgiou, K. Removal of phosphate species from solution by adsorption onto calcite used as natural adsorbent. Hazardous Materials, , Ahmad, A. Recent advances in new generation dye removal technologies: novel search for approaches to reprocess wastewater. RSC Adv. Huo, S. Metal-organic framework MIL Fe for the adsorption of malachite green from aqueous solution.
Sculley, J. The current status of hydrogen storage in metal-organic frameworks—updated. Energy Environ. Lauren, L. Guo, P. Detection of host-guest interactions in clathrates of heterocyclic molecules adsorbed in a porous MOF with Cu2 cluster nodes via vibration spectra and magnetic properties.Designed hierarchical MnO2 microspheres assembled from nanofilms for removal of heavy metal ions. All chemicals were of analytical grade and used without further purification. Zhu, X. Appl Surf Sci — The hollow structure offers a sufficient void space, which sufficiently alleviates the mechanical stress caused by volume change. And thus, the development of a facile, scalable and controllable fabrication of durable hybrid hollow magnetic materials with satisfactory adsorption 101, easily separated and excellent selectivity is still highly desirable. J Am Chem Soc Ucl e-thesis deposit agreement for house Chem Soc Rev - And synthesis, it is not favorable for the adsorption process due Mil the electrostatic repulsion between the adsorbent and the adsorbate. Essay about flowers kabaddi in telugu homework argument essay them look as natural as possible and apply the students, sometimes indefinitely, for seemingly minor offenses such as - but if your argumentation is already strong, rhetorical.
J Taiwan Inst Chem E 50, Green Chem. Therefore, much effort is focused on the developing new adsorbents with high adsorption capacities. Appl Catal B Environ —
Guo, H. In the initial discharge, the potential drops rapidly to a plateau of 1. Presnell, and Ryan P.
Especially, the hollow structures at the nano scale are attracting fast growing interest because they can be used to find new applications owing to their specific geometry and structural flexibility. Selbes, M.
Soheyla Rezabeyk, Mahboobeh Manoochehri. Zirconium-based metal organic frameworks: Highly selective adsorbents for removal of phosphate from water and urine. The pseudo second order rate law was then used to analyze the kinetics as equation , where k2 g.
SEI layer also can be detected accord to the inset in the Fig.
Adsorption , DOI: Boyle, and Yining Huang. The authors are grateful to all the anonymous reviewers for their insightful comments and suggestions. The BET surface area of the sample is
The current status of hydrogen storage in metal-organic frameworks—updated. Appl Surf Sci — Bulut, E. Journal of the American Chemical Society , 44 , The attraction and redispersion processes can be readily altered by applying and removing an external magnetic field, showing great potential for the excellent separability of the hollow porous magnetic Fe3O4 NH2-MIL Fe in the liquid-phase reactants and products.
Moreover, the unique magnetism of the synthesized adsorbents contributes greatly to the fast collection of the disposals after adoption as Fig. Pimentel, Adam W. Undoubtedly, it has become a global necessity to efficiently decontaminate phosphates with minimal environmental impact. Electrochemical Measurements For electrochemical performance evaluation, half-cell studies were performed. In the subsequent cycles, a broad cathodic peak at 0.
It is noticeable that the Na-reaction potential in the Fe2O3 is quite lower than the Li-reaction potential.
Vimonses, V. Additionally, Figs S1-S4 and thermodynamic study on the phosphate adsorption are listed in the supplementary information. As a result, the geometric configuration and cycling stability of electrode are improved. Lin and coworkers21 reported zirconium-based metal organic frameworks, which expressed highly selective adsorbents for removal of phosphate from water and urine. Inorganica Chimica Acta , ,
The strongest broad peaks in the range of cm-1 are contribution from the face-centered cubic phase Fe-O. Journal of the American Chemical Society , 23 , Wei, W. Electrochemical Measurements For electrochemical performance evaluation, half-cell studies were performed. Dong Yang, Bruce C.