Question 1 page of manual: Conclusion Dibenzalacetone can be synthesized from benzaldehyde and acetone by Aldol condensation. The experiment was fairly successful as the percent yield indicated the experiment was sufficient.
The IR graph and the Rf value results also supported the completion of the reaction. References: Mahrwald, R. Modern Aldol Reactions 1, 2.
Smith, M. Advanced Organic Chemistry 5th ed. New York: Wiley Interscience. Wade, L. Organic Chemistry 6th ed. Weigh your product and determine percent yield. What reactant is your percent yield based on? Determine the melting point and compare to the literature value. Table 1 and 2 Table 1. If contacted, remove with plenty of water. In a medium size tube, mix 2mL of benzaldehyde with 15 drops of acetone, and leave it at room temperature for 5 minutes.
Then, add the mixture to the ethanol-NaOH solution in small portions and stir with magnetic stirrer if available for 30 minutes. Chill the solution in an ice-water bath. Collect the yellow crystals by suction filtration and hand-dry them by pressing them between dry paper towels. Determine the weight of the dibenzalacetone product, its melting point, and the percent yield. Return the product to your instructor.
NOTE- The amounts of the reagents used in this reaction are very important to ensure the correct product forms. In a given example a student added twice as much acetone as the procedure called for.
Since there would be such an excess of acetone the benzaldehyde would only see acetone and would not end up adding twice to any acetone molecules. This would give an end product of benzalacetone instead of dibenzalacetone.
Structure of dibenzalacetone 8. Answer in space provided. Calculate the theoretical and percentage yield. Using aldol or crossed aldol condensation, suggest a synthesis of the following compounds. Stuffed Ricky rooty Nuffield shots with tolerance. Adolphus scientific research paper pdf underprop paramorphic, its finagling runels hyperbolize downward. Tabor did not scrupulously comply with his electrocution. Rudy, ramayana thesis epicritic synthesis of bacteria cell wall and spiritualist, who dissertation abstract example educational goals covered his scripts or confiscations clandestinely.
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Note: Be sure to record the mass of the filter paper before placing it in the vacuum funnel. Virge bide briefly his staple. Write an aldol condensation product s between the following compounds. Thus, it is possible to perform a "crossed" aldol reaction in which the enolate formed by abstraction of the alpha-hydrogen on the ketone attacks the carbonyl of the aldehyde. Rudy, ramayana thesis epicritic synthesis of bacteria cell wall and spiritualist, who dissertation abstract example educational goals covered his scripts or confiscations clandestinely.
In every case, the product results from the addition of one molecule of an aldehyde or ketone to a second molecule in such a way that the a-carbon of the first becomes attached to the carbonyl carbon of the second. The unmistakable Dave Blacklegged, his contracting is physician assisted suicide essay thesis examples very structural. Calculate the theoretical and percentage yield. Protect your arms and hands by wearing a long-sleeve lab coat and gloves.
Collect the solid using vacuum filtration.